Chemical fact sheet: Peonidin 3-O-(p-coumaroylglucoside)

Peonidin 3-O-(p-coumaroylglucoside)

Basics

Category
Anthocyanidin derivatives
IUPAC-name
5,7-dihydroxy-2-(4-hydroxy-3-methoxyphenyl)-3-(((3S,4R,5R,6S)-3,4,5-trihydroxy-6-((((E)-3-(4-hydroxyphenyl)acryloyl)oxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)chromenylium chloride
Formula
No formula stored
Exact mass
644.12967 g/mol
Molecular weight
No weights stored
Structure
Chemical structure of peonidin 3-O-(p-coumaroylglucoside)
Figure 1.1: Chemical structure of peonidin 3-O-(p-coumaroylglucoside)

Sources

In summary, the chemical peonidin 3-O-(p-coumaroylglucoside) has been analyzed from following sources:

Urtica dioica 'Clone13'
1st 2nd

Note that an analysis result in the database may indicate either presence or lack thereof of a chemical in an analyzed sample.

References

  1. P. Pinelli, F. Ieri, P. Vignolini, L. Bacci, S. Baronti, and A. Romani, "Extraction and HPLC analysis of phenolic compounds in leaves, stalks, and textile fibers of Urtica dioica L.," Journal of Agricultural and Food Chemistry , vol. 56 , pp. 9127–9132 , DOI: 10.1021/jf801552d .

Analysis results

Analysis result 1

Detection technique Values Units
M⁺ 609 m/z
MS²⁺ 301
463 		m/z
STD
False
TLC
False
UV/Vis detector description
HPLC-DAD, diode array detector
Mass spectrometer description
HPLC-MS, HPLC-MS/MS, triple quadrupole, electrospray, turbo ion spray
Organism
Urtica dioica 'Clone13'
cultivated
powdered, frozen
Collection dates
2006-7
Sample note
The nettle cultivar "Clone" was growing in Prato, Italy at the experimental site. The stalks were frozen in liquid nitrogen and comminuted into a powder. The extraction was performed with 70 % EtOh and pH was adjusted to 3.2 and 2.0 by HCOOH. The raw extract was defatted with n-hexane, dried and adjusted to a final volume with 70 % EtOH.
Extraction solvents
70 % EtOH, HCOOH
Extraction mass/volume-ratio
20 mg/mL
Extraction repeats
3
Extraction temperature
20±5 °C
Extract drying method
dried under vacuum
Analysis solvents
70 % EtOH
Detection note
m/z 609 and the loss of p-coumaroyl moiety [M - 146]+ produced 463; and the loss of p-coumaroylglucoside [M - 308]+ produced 301 (peonidin aglycon)
References

P. Pinelli, F. Ieri, P. Vignolini, L. Bacci, S. Baronti, and A. Romani, "Extraction and HPLC analysis of phenolic compounds in leaves, stalks, and textile fibers of Urtica dioica L.," Journal of Agricultural and Food Chemistry , vol. 56 , pp. 9127–9132 , DOI: 10.1021/jf801552d .

Analysis result 2

Detection technique Values Units
M⁺ 609 : ND m/z
STD
False
TLC
False
UV/Vis detector description
HPLC-DAD, diode array detector
Mass spectrometer description
HPLC-MS, HPLC-MS/MS, triple quadrupole, electrospray, turbo ion spray
Organism
Urtica dioica 'Clone13'
cultivated
powdered, frozen
Collection dates
2006-7
Sample note
The nettle cultivar "Clone" was growing in Prato, Italy at the experimental site. The leaves were frozen in liquid nitrogen and comminuted into a powder. The extraction was performed with 70 % EtOH and pH adjusted to 3.2 and 2.0 by HCOOH. The raw extract was defatted with n-hexane, dried and adjusted to a final volume with 70 % EtOH.
Extraction solvents
70 % EtOH, HCOOH
Extraction mass/volume-ratio
20 mg/mL
Extraction repeats
3
Extraction temperature
20±5 °C
Analysis solvents
70 % EtOH
References

P. Pinelli, F. Ieri, P. Vignolini, L. Bacci, S. Baronti, and A. Romani, "Extraction and HPLC analysis of phenolic compounds in leaves, stalks, and textile fibers of Urtica dioica L.," Journal of Agricultural and Food Chemistry , vol. 56 , pp. 9127–9132 , DOI: 10.1021/jf801552d .