Chemical fact sheet: Monotropitin

Monotropitin

Basics

Category
Salicylate derivatives & simple phenolics
IUPAC-name
methyl 2-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-((((2S,3R,4S,5R)-3,4,5-trihydroxytetrahydro-2H-pyran-2-yl)oxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)benzoate
Formula
No formula stored
Exact mass
446.14243 g/mol
Molecular weight
No weights stored
Structure
Chemical structure of monotropitin
Figure 1.1: Chemical structure of monotropitin

Sources

In summary, the chemical monotropitin has been analyzed from following sources:

Filipendula ulmaria  (L.) Maxim.
1st 2nd

Note that an analysis result in the database may indicate either presence or lack thereof of a chemical in an analyzed sample.

References

  1. B. Blazics, I. Papp, and Á. Kéry, "LC-MS qualitative analysis and simultaneous determination of six Filipendula salicylates with two standards.," Chromatographia , vol. 71 , pp. S61–S677 , DOI: 10.1365/s10337-010-1502-4 .
  2. D. Popowski, K. Pawłowska, J. Piwowarski, and S. Granica, "Gut microbiota-assisted isolation of flavonoids with a galloyl moiety from flowers of meadowsweet, Filipendula ulmaria (L.) Maxim.," Phytochemistry Letters , vol. 30 , pp. 220–223 , DOI: 10.1016/j.phytol.2018.12.003 .

Analysis results

Analysis result 1

Detection technique Values Units
[M⁻ H]⁻ 491 m/z
MS²⁻ 89
125
151 		m/z
STD
False
TLC
False
UV/Vis detector description
LC-DAD
Mass spectrometer description
LC-DAD-ESI-MS-MS, LC-ESI-MS-MS, triple quadrupole
Organism
Filipendula ulmaria  (L.) Maxim.
wild
dried, powdered
Collection dates
2007-6
Sample note
Filipendula ulmaria L. Maxim plant samples; herb and flower (Filipendulae herba and flos) were collected and identification was performed in the Department of Pharmacognosy, Semmelweis University, where the voucher specimens is deposited.
Drying methods
air-dried
Extraction solvents
methanol
Extraction repeats
1
Extract drying method
evaporation under reduced pressure
Extract drying temperature
50 °C
Analysis solvents
70 % methanol
Detection note
Formate adduct [M – H + HCOOH]– ; the loss of 294 indicated of primverose and the abundant fragment m/z salicylaldehyde.
References

B. Blazics, I. Papp, and Á. Kéry, "LC-MS qualitative analysis and simultaneous determination of six Filipendula salicylates with two standards.," Chromatographia , vol. 71 , pp. S61–S677 , DOI: 10.1365/s10337-010-1502-4 .

Analysis result 2

Detection technique Values Units
UV/Vis 276 nm
[M⁺ H]⁺ 464 m/z
[M⁻ H]⁻ 491 m/z
MS²⁻ 293
413
445 		m/z
STD
False
TLC
False
UV/Vis detector description
HPLC-DAD
Mass spectrometer description
ESI-MS, HPLC-DAD/MSn
Organism
Filipendula ulmaria  (L.) Maxim.
cultivated
fresh
Sample note
Meadowsweet flowers (Filipendula ulmariae flos) were collected from the Garden of Medical Plants of the Department of Pharmacognosy, Medical University of Lublin. A voucher specimen (No. 09-09-2017_A) was deposited in the Garden of Medical Plants collection. The plant material was identified by Sebastian Granica.
Extraction solvents
boiling water
Extraction repeats
2
Extract drying method
freeze-drying
Analysis solvents
water
References

D. Popowski, K. Pawłowska, J. Piwowarski, and S. Granica, "Gut microbiota-assisted isolation of flavonoids with a galloyl moiety from flowers of meadowsweet, Filipendula ulmaria (L.) Maxim.," Phytochemistry Letters , vol. 30 , pp. 220–223 , DOI: 10.1016/j.phytol.2018.12.003 .