Chemical fact sheet: Chrysoeriol 6,8-di-C-glucoside

The BCDB-database is not an authoritative database. This sheet collates data stored for chemical entry chrysoeriol 6,8-di-C-glucoside and its related chemical compound entries stellarin-2 .

Chrysoeriol 6,8-di-C-glucoside

Basics

Category
Flavone and flavonol derivatives
IUPAC-name
5,7-dihydroxy-2-(4-hydroxy-3-methoxyphenyl)-6,8-bis(3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)-4H-chromen-4-one
Formula
No formula stored
Exact mass
624.16900 g/mol
Molecular weight
624.50000 g/mol
Structure
Chemical structure of chrysoeriol 6,8-di-C-glucoside
Figure 1.1: Chemical structure of chrysoeriol 6,8-di-C-glucoside

Sources

In summary, the chemical chrysoeriol 6,8-di-C-glucoside has been analyzed from following sources:

Isatis indigotina
1st
Isatis tinctoria French Woad  L.
1st 2nd
Isatis tinctoria Thüringer Waid  L.
1st

Note that an analysis result in the database may indicate either presence or lack thereof of a chemical in an analyzed sample.

References

  1. M. Tobias, I. Plitzko, and M. Hamburger, "A comprehensive metabolite profiling of Isatis tinctoria leaf extracts.," Phytochemistry , vol. 70 , no. 7 , pp. 924-934 , DOI: 10.1016/j.phytochem.2009.04.019 .
  2. T. Nguyen, A. Jamali, E. Grand, K. Morreel, P. Marcelo, E. Gontier, and R. Dauwe, "Phenylpropanoid profiling reveals a class of hydroxycinnamoyl glucaric acid conjugates in Isatis tinctoria leaves," Phytochemistry , vol. 144 , pp. 127–140 , DOI: 10.1016/j.phytochem.2017.09.007 .
  3. T. Nguyen, P. Marcelo, E. Gontier, and R. Dauwec, "Metabolic markers for the yield of lipophilic indole alkaloids in dried woad leaves (Isatis tinctoria L.).," Phytochemistry , vol. 163 , pp. 89-98 , DOI: 10.1016/j.phytochem.2019.04.006 .

Analysis results

Analysis result 1

Detection technique Values Units
UV/Vis 210
270
343 		nm
[M⁺ H]⁺ 625 m/z
[M⁻ H]⁻ 623 m/z
MS²⁻ 383
503
533
605 		m/z
STD
False
TLC
False
UV/Vis detector description
HPLC-PDA, photodiode array (PDA)
Mass spectrometer description
HPLC-ESI-MS, ion trap, HPLC-TOF-MS, APCI
Organism
Isatis tinctoria Thüringer Waid  L.
cultivated
ground, dried, cut into small pieces
Collection dates
2003-9
Sample note
The plants were cultivated on the experimental plots of the Agricultural Research Station of Thuringia (TLL), Dornburg, Germany. Specimens of seeds from the strains are kept at the TLL, under accessions number 153/PG 1 (Thüringer Waid).
Drying methods
oven-dried
Drying temperature
40 °C
Dried material storage temperature
15 °C
Dried material storage notes
dark; in the brown glass bottles
Extraction solvents
methanol
Extraction repeats
2
Extraction time
12 min
Extraction temperature
70 °C
Analysis solvents
MeOH
Detection note
[M + Na]+ = 647
References

M. Tobias, I. Plitzko, and M. Hamburger, "A comprehensive metabolite profiling of Isatis tinctoria leaf extracts.," Phytochemistry , vol. 70 , no. 7 , pp. 924-934 , DOI: 10.1016/j.phytochem.2009.04.019 .

Analysis result 2

Detection technique Values Units
UV/Vis 210
270
343 		nm
[M⁺ H]⁺ 625 m/z
[M⁻ H]⁻ 623 m/z
MS²⁻ 383
503
533
605 		m/z
STD
False
TLC
False
UV/Vis detector description
HPLC-PDA, photodiode array (PDA)
Mass spectrometer description
HPLC-ESI-MS, ion trap, HPLC-TOF-MS, APCI
Organism
Isatis indigotina
cultivated
ground, dried, cut into small pieces
Collection dates
2003-9
Sample note
The plants were cultivated on the experimental plots of the Agricultural Research Station of Thuringia (TLL), Dornburg, Germany. Specimens of seeds from the strains are kept at the TLL, under accessions number 153 PG 12 (I. indigotina).NOTE. There are conflicting views on the taxonomy of I. tinctoria (European woad) and I. indigotica (Chinese woad). I. indigotina was described for the first time by Fortune in 1846, and initially considered as a distinct species. Afterward, some taxonomists have classified it as a variety of I. tinctoria. Nowadays, I. indigotina is considered as a synonym of I. tinctoria [e.g. The Plant List, IPNI (International Plant Name Index), Tropicos]. (Speranzo et al. 2020). In this database, we use the names similarly as the authors.
Drying methods
oven-dried
Drying temperature
40 °C
Dried material storage temperature
15 °C
Dried material storage notes
dark; in the brown glass bottles
Extraction solvents
methanol
Extraction repeats
2
Extraction time
12 min
Extraction temperature
70 °C
Analysis solvents
MeOH
Detection note
[M + Na]+ = 647
References

M. Tobias, I. Plitzko, and M. Hamburger, "A comprehensive metabolite profiling of Isatis tinctoria leaf extracts.," Phytochemistry , vol. 70 , no. 7 , pp. 924-934 , DOI: 10.1016/j.phytochem.2009.04.019 .

Analysis result 3

Detection technique Values Units
[M⁻ H]⁻ 623.16070 m/z
MS²⁻ 341
503
504
533
534
605 		m/z
STD
False
TLC
False
UV/Vis detector description
Mass spectrometer description
ESI, LTQ orbitrap, LTQ linear ion trap
Organism
Isatis tinctoria French Woad  L.
cultivated
fresh, frozen, cut into small pieces, frozen in liquid nitrogen
Sample note
The seeds were provided by the botanical garden of Amiens (Jardin des Plantes), France, where specimens of seeds from the strain were kept under accession number 061003-3. The seeds were sown in soil and grown in a greenhouse at 16h/8h day/night regime, 24 C, 70% moisture. The samples ere taken from 11-week-old plants at the rosette stage.
Extraction solvents
methanol
Extraction repeats
2
Extraction time
10 min
Extraction temperature
70 °C
Extract drying method
evaporation in the speed vacuum
Analysis solvents
water: MeOH
References

T. Nguyen, A. Jamali, E. Grand, K. Morreel, P. Marcelo, E. Gontier, and R. Dauwe, "Phenylpropanoid profiling reveals a class of hydroxycinnamoyl glucaric acid conjugates in Isatis tinctoria leaves," Phytochemistry , vol. 144 , pp. 127–140 , DOI: 10.1016/j.phytochem.2017.09.007 .

Analysis result 4

Detection technique Values Units
[M⁻ H]⁻ 623.16070 m/z
STD
False
TLC
False
UV/Vis detector description
Mass spectrometer description
ESI, LTQ orbitrap, LTQ linear ion trap
Organism
Isatis tinctoria French Woad  L.
cultivated
fresh, frozen, frozen in liquid nitrogen
Sample note
The seeds of Isatis tinctoria L.(strain French Woa; accession number 061003-3) were provided by the botanical garden of Amiens (Jardin des Plantes), France. They were sown in soil and plantlets were grown in greenhouse under the following conditions: 24 °C, 70% moisture and photoperiod 16h. Rosette leaves were harvested from 11-week-old woad plants.
Extraction solvents
methanol
Extraction repeats
2
Extraction time
10 min
Extraction temperature
70 °C
Extract drying method
evaporation in the speed vacuum
Analysis solvents
water: MeOH
Detection note
See. Nguyen et al. 2017 (MS-fragments)
References

T. Nguyen, P. Marcelo, E. Gontier, and R. Dauwec, "Metabolic markers for the yield of lipophilic indole alkaloids in dried woad leaves (Isatis tinctoria L.).," Phytochemistry , vol. 163 , pp. 89-98 , DOI: 10.1016/j.phytochem.2019.04.006 .

Stellarin-2

Basics

Category
None
IUPAC-name
5,7-dihydroxy-2-(4-hydroxy-3-methoxyphenyl)-6,8-bis((2S,3R,4R,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)-4H-chromen-4-one
Formula
No formula stored
Exact mass
624.16903 g/mol
Molecular weight
No weights stored
Structure
Chemical structure of stellarin-2
Figure 2.1: Chemical structure of stellarin-2

Sources

No links to any potential source for this chemical in the database.

References

Analysis results

No analysis results for this entry in the database.